林锦鸿

创建时间:  2021/04/12  张杰   浏览次数:   返回

林锦鸿 个人简介

 

姓名:林锦鸿

出生日期:1983-2-8

办公室:E510

职称:副教授

学历:博士

职务:

通信地址:上海市宝山区上大路99号

电话:

Email:jlin@shu.edu.cn

【个人简历】

2001/9-2005/7:   东华大学,学士

2005/9-2011/1:中科院上海有机化学研究所,博士,导师:肖吉昌研究员

2011/3-2013/2:纽约州立大学Albany分校,博士后,导师:John T. Welch

2013/3-2021/4:中科院上海有机化学研究所,副研究员

2021/4-至   今:上海大学化学系,副教授

 

【研究方向】

有机氟化学、过渡金属催化 

 

【人才项目】

2019年入选中科院青年创新促进会

 

【科研项目】

(1)上海市科学技术委员会自然科学基金面上项目,项目批准号:22ZR142360020万,202204月至 2025 03月,主持

(2)国家自然科学基金青年项目,非活化Csp3-H键的三氟甲基化,项目批准号:2150221425万,201601月至 2018 12月,主持,已结题

(3)上海市科学技术委员会自然科学基金项目,不对称催化三氟甲基化,项目编号:14ZR144880010万,201407月至201706月,主持,已结题

 

【论文著作】:第一作者或通讯作者文章(按时间倒序排列)

1. Zhu, Y.-R.; Lin, J.-H.; Xiao, J.-C., Triphenylphosphine/1,2-Diiodoethane-Promoted Formylation of Indoles with N,N-Dimethylformamide. Synlett 2022, 33, 259-263.

2. Qian, B.-Y.; Zhang, W.; Lin, J.; Cao, W.; Xiao, J.-C., anti-Markovnikov Iodofluorination of Alkenes. Chem. Asian J. 2022, accepted.

3. Hu, Y.; Wang, X.; Ren, N.; Li, N.; Li, J.; Chen, J.; Zhang, H.; Deng, H.; Cao, W.; Lin, J.-H., A Convenient Synthesis of Fluoroalkylated Benzimidazole- or Indole-fused Benzoxazines. Eur. J. Org. Chem. 2022, e202101501.

4. Zhou, W.; Pan, W.-J.; Chen, J.; Zhang, M.; Lin, J.-H.; Cao, W.; Xiao, J.-C., Transition-metal difluorocarbene complexes. Chem. Commun. 2021, 57, 9316-9329.

5. Yang, Y.-F.; Lin, J.-H.; Xiao, J.-C., Starting from Styrene: A Unified Protocol for Hydrotrifluoromethylation of Diversified Alkenes. Org. Lett. 2021, 23, 9277-9282.

6. Wu, W.-F.; Lin, J.-H.; Xiao, J.-C.; Cao, Y.-C.; Ma, Y., Recent Advances in the Synthesis of CF3- or HCF2-Substituted Cyclopropanes. Asian J. Org. Chem. 2021, 10, 485-495.

7. Wang, X.; Sun, X.; Li, N.; Chen, J.; Zhang, H.; Deng, H.; Lin, J.-H.; Cao, W., The synthesis of perfluoroalkylated indolizines via tandem cyclization/aromatization. J. Fluorine Chem. 2021, 251, 109900.

8. Hu, Y.; Ye, L.; Chen, J.; Zhang, H.; Deng, H.; Lin, J.-H.; Cao, W., An Efficient Construction of CF3-Substituted Spirooxindole-Fused Benzo[a]quinolizidines by a Three-Component Cyclization. Eur. J. Org. Chem. 2021, 4405-4408.

9. He, G.; Xiao, X.; Jin, H.-Z.; Lin, J.-H.; Zhong, T.; Zheng, X.; Xiao, J.-C., Ph2S/selectfluor-promoted deoxydifluorination of aldehydes. Tetrahedron 2021, 83, 131963.

10. Hao, F.; Shang, X.; Liu, Z.; Zhang, H.; Lin, J.-H.; Xiao, J.-C., Rh-catalyzed tunable defluorinative borylation. Chem. Commun. 2021, 57, 7124-7127.

11. Zhang, Y.-X.; Xiao, X.; Fu, Z.-H.; Lin, J.-H.; Guo, Y.; Yao, X.; Cao, Y.-C.; Du, R.-B.; Zheng, X.; Xiao, J.-C., Difluorocarbene-Based Cyanation of Aryl Iodides. Synlett 2020, 31, 713-717.

12. Zhang, W.; Gu, Y. C.; Lin, J.-H.; Xiao, J.-C., Dehydroxylative Fluorination of Tertiary Alcohols. Org. Lett. 2020, 22, 6642-6646.

13. Xu, Z.-W.; Zhang, W.; Lin, J.-H.; Jin, C. M.; Xiao, J.-C., Pd‐catalyzed transfer of difluorocarbene for three component cross‐coupling. Chin. J. Chem. 2020, 38, 16471650.

14. Xiao, X.; Zheng, Z.-T.; Li, T.; Zheng, J.-L.; Tao, T.; Chen, L.-M.; Gu, J.-Y.; Yao, X.; Lin, J.-H.; Xiao, J.-C., Recent Advances in Difluoromethylthiolation. Synthesis 2020, 52, 197-207.

15. Xiao, X.; Yao, X.; Yu, J.; Tang, T.; Xiao, C.; Gu, J.; Lin, J.-H.; Zheng, X.; Xiao, J.-C., A one-step synthesis of gem-difluoroolefins from alcohols. J. Fluorine Chem. 2020, 240, 109649.

16. Lin, J.-H.; Xiao, J.-C., Fluorinated Ylides/Carbenes and Related Intermediates from Phosphonium/Sulfonium Salts. Acc. Chem. Res. 2020, 53, 1498-1510.

17. He, G.; Jiang, Y.-H.; Xiao, X.; Lin, J.-H.; Zheng, X.; Du, R.-B.; Cao, Y.-C.; Xiao, J.-C., Difluorocarbene-based trifluoromethylthiolation of terminal alkynes. J. Fluorine Chem. 2020, 230, 109437.

18. Long, J.; Chen, J.; Li, R.; Liu, Z.; Xiao, X.; Lin, J.-H.; Zheng, X.; Xiao, J.-C., Ph3P/I–-Promoted Dichlorination or Dibromination of Epoxides with XCH2CH2X (X = Cl or Br). Synlett 2019, 30, 181-184.

19. Liu, Z.; Long, J.; Xiao, X.; Lin, J.-H.; Zheng, X.; Xiao, J.-C.; Cao, Y.-C., Ph3P+CF2CO2- as an F- and :CF2 source for trifluoromethylthiolation of alkyl halides. Chin. Chem. Lett. 2019, 30, 714 - 716.

20. Li, C.-G.; Xie, Q.; Xu, X.-L.; Wang, F.; Huang, B.; Liang, Y.-F.; Xu, H.-J., Silver-Catalyzed Decarboxylative Alkylfluorination of Alkenes. Org. Lett. 2019, 21, 8496-8500.

21. Zhao, Y.; Lin, J.-H.; Hang, X.-C.; Xiao, J.-C., Ag-Mediated Trifluoromethylthiolation of Inert Csp3–H Bond. J. Org. Chem. 2018, 83, 14120-14125.

22. Zhang, W.; Lin, J.-H.; Xiao, J.-C., Cu-catalyzed chlorotrifluoromethylation of alkenes with CF3SO2Cl. J. Fluorine Chem. 2018, 215, 25-31.

23. Zhang, W.; Chen, J.; Lin, J.-H.; Xiao, J.-C.; Gu, Y.-C., Rapid Dehydroxytrifluoromethoxylation of Alcohols. iScience 2018, 5, 110-117.

24. Pan, X.-Y.; Zhao, Y.; Qu, H.-A.; Lin, J.-H.; Hang, X.-C.; Xiao, J.-C., Tri- and di-fluoroethylation of alkenes by visible light photoredox catalysis. Org. Chem. Front. 2018, 5, 1452-1456.

25. Zeng, X.-L.; Deng, Z.-Y.; Liu, C.; Zhao, G.; Lin, J.-H.; Zheng, X.; Xiao, J.-C., Nucleophilic monofluoroalkylation with fluorinated phosphonium salt toward carbonyl and imine compounds. J. Fluorine Chem. 2017, 193, 17-23.

26. Yu, J.; Lin, J.-H.; Xiao, J.-C., Reaction of Thiocarbonyl Fluoride Generated from Difluorocarbene with Amines. Angew. Chem. Int. Ed. 2017, 56, 16669-16673.

27. Luo, J.-J.; Zhang, M.; Lin, J.-H.; Xiao, J.-C., Difluorocarbene for Dehydroxytrifluoromethylthiolation of Alcohols. J. Org. Chem. 2017, 82, 11206-11211.

28. Huang, Q.-X.; Zheng, Q.-T.; Duan, Y.; Lin, J.-H.; Xiao, J.-C.; Zheng, X., Diastereoselective Synthesis of CF3-Containing Vicinal Diamines. J. Org. Chem. 2017, 82, 8273-8281.

29. Duan, Y.; Lin, J.-H.; Xiao, J.-C.; Gu, Y.-C., Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P). Org. Chem. Front. 2017, 4, 1917-1920.

30. Duan, Y.; Lin, J.-H.; Xiao, J.-C.; Gu, Y.-C., Difluoromethylcarbene for iron-catalyzed cyclopropanation. Chem. Commun. 2017, 53, 3870 - 3873.

31. Zheng, Q.-T.; Wei, Y.; Zheng, J.; Duan, Y.-y.; Zhao, G.; Wang, Z.-B.; Lin, J.-H.; Zheng, X.; Xiao, J.-C., Difluoromethylation of N-arylsulfonyl hydrazones with difluorocarbene leading to difluoromethyl aryl sulfones. RSC Adv. 2016, 6, 82298-82300.

32. Wei, Y.; Yu, L.; Lin, J.; Zheng, X.; Xiao, J., DBU-Promoted Trifluoromethylation of Aryl Iodides with Difluoromethyltriphenylphosphonium Bromide. Chin. J. Chem. 2016, 34, 481-484.

33. Liu, C.; Deng, X.-Y.; Zeng, X.-L.; Zhao, G.; Lin, J.-H.; Wang, H.; Xiao, J.-C., Base-free O-difluoromethylation of 1,3-diones with difluorocarbene. J. Fluorine Chem. 2016, 192, 27-30.

34. Ji, Y.-L.; Luo, J.-J.; Lin, J.-H.; Xiao, J.-C.; Gu, Y. C., Cu-Catalyzed C-H Trifluoromethylation of 3-Arylprop-1-ynes for the Selective Construction of Allenic Csp(2)-CF3 and Propargyl Csp(3)-CF3 Bonds. Org. Lett. 2016, 18, 1000-1003.

35. Duan, Y.; Lin, J.-H.; Xiao, J.-C.; Gu, Y. C., A Trifluoromethylcarbene Source. Org. Lett. 2016, 18, 2471-2474.

36. Deng, Z.; Liu, C.; Zeng, X.-L.; Lin, J.-H.; Xiao, J.-C., Nucleophilic 1,1-Difluoroethylation with Fluorinated Phosphonium Salt. J. Org. Chem. 2016, 81, 12084 - 12090.

37. Lin, J.-H.; Ji, Y.-L.; Xiao, J.-C., Recent Advances in C-H Trifluoromethylthiolation and Trifluoromethoxylation Reactions. Curr. Org. Chem. 2015, 19, 1541-1553.

38. Lin, J.-H.; Xiao, J.-C., Recent advances in asymmetric fluorination and fluoroalkylation reactions via organocatalysis. Tetrahedron Lett. 2014, 55, 6147-6155.

39. Ji, Y.-L.; Lin, J.-H.; Xiao, J.-C.; Gu, Y.-C., Copper-catalyzed tandem trifluoromethylation/cyclization of internal alkynes. Org. Chem. Front. 2014, 1, 1280-1284.

40. Ji, Y.-L.; Lin, J.-H.; Xiao, J.-C.; Gu, Y.-C., Stereoselective Synthesis of α-Trifluoromethyl Enones by AuI/CuI-Co-Catalyzed Tandem 1,3-Acyloxy Migration/Trifluoromethylation Reaction of Propargyl Acetates. Eur. J. Org. Chem. 2014, 7948-7954.

41. Ji, Y.-L.; Kong, J.-J.; Lin, J.-H.; Xiao, J.-C.; Gu, Y.-C., Copper-mediated trifluoromethylation of propargyl acetates leading to trifluoromethyl-allenes. Org. Biomol. Chem. 2014, 12, 2903-2906.

42. Lin, J.-H.; Zong, G.; Du, R.-B.; Xiao, J.-C.; Liu, S., The asymmetric synthesis of CF3- or -CF2-substituted tetrahydroquinolines by employing a chiral phosphoric acid as catalyst. Chem. Commun. 2012, 48, 7738-40.

43. Lin, J.-H.; Xiao, J.-C., The Asymmetric Friedel-Crafts Reaction of Indoles with Fluoroalkylated Nitroalkenes Catalyzed by Chiral Phosphoric Acid. Eur. J. Org. Chem. 2011, 4536-4539.

44. Lin, J.-H.; Zhang, C.-P.; Zhu, Z.-Q.; Chen, Q.-Y.; Xiao, J.-C., A novel pyrrolidinium ionic liquid with 1,1,2,2-tetrafluoro-2-(1,1,2,2-tetrafluoroethoxy)ethanesulfonate anion as a recyclable reaction medium and efficient catalyst for Friedel–Crafts alkylations of indoles with nitroalkenes. J. Fluorine Chem. 2009, 130, 394-398.

45. Lin, J.-H.; Zhang, C.-P.; Xiao, J.-C., Enantioselective aldol reaction of cyclic ketones with aryl aldehydes catalyzed by a cyclohexanediamine derived salt in the presence of water. Green Chem. 2009, 11, 1750-1753.

 

 

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