报告题目 (Title)：Gold Catalysis and Possibilities in Materials Science/金催化及其在材料科学中的应用

报告人 (Speaker)： Stephen K. Hashmi 教授（Heidelberg University）

报告时间 (Time)：2023年08月31日(周四) 15:00-16:00

报告地点 (Place)：校本部乐乎新楼思源厅

邀请人(Inviter)：于洋 教授

主办部门：理学院化学系

报告摘要：

Triggered by new reactivity patterns discovered in 2000,[1] gold catalysis has become a very successful sector of catalysis research.[2] After methodology development and mechanistic studies in the last years applications in total synthesis became a hot topic in gold catalysis. Typical intermediates would be vinylgold/arylgold species or gold carbene species, recently also gold vinylidene intermediates,[3] in the last two years even photoredox catalysis with gold complexes evolved, including catalytic cycles involving gold (I) and gold (III).[4] Gold-catalyzed reactions involving functionalized gold carbene intermediates represent another new and significant variation of the reactivity patterns of gold catalysis. New reactivity patterns will be discussed in detail with a number of new reactions, the presentation will combine both experimental and computational results. Examples will involve the use of anthranils, 1,2,4-oxadiazoles and 1,3,5-triazinanes. Furthermore, oxygen transfer to the functionalized carbene centers and insertions into alkyl-C,H bonds will be addressed in detail.

报告人简介：

Chemistry at the University of Munich (LMU), Germany

1983 Studies of Chemistry at LMU München, Diploma thesis 1988

Doctoral thesis 1991,both with Prof. G. Szeimies, on highly strained organic compounds

Postdoctoral studies in the group of Prof. B. M. Trost at Stanford University, California, USA

Enyne metathesis and related reactions, 1991-1993

Habilitation in the group of Prof. Dr. J. Mulzer, 1993-1998

Institute of Organic Chemistry of Free University Berlin, Germany

Institute of Organic Chemistry of University of Frankfurt, Germany

Institute of Organic Chemistry of University of Vienna, Austria

Visiting scientist at the University of Tasmania, Hobart, Australia, 07/1999–10/1999

Temporary Professorship for organic chemistry at the Department of Chemistry of University of Marburg, Germany, 11/1999–07/2000

Professor for Organic Chemistry at the Institute of Organic Chemistry of University of Stuttgart, Germany, 03/2001–03/2007

Chair for Organic Chemistry at the Institute of Organic Chemistry of Heidelberg University, Germany, since 04/2007

Director of the Institute of Organic Chemistry of Heidelberg University, Germany, 10/2008-09/2010

Dean of the Department of Chemistry and Earth Sciences of Heidelberg University, Germany, 10/2010-09/2012

Vice Dean of the Department of Chemistry and Earth Sciences of Heidelberg University, Germany, 10/2012-09/2013

Vice Rector for Research and Transfer of Heidelberg University, for two continuous terms, 10/2013-09/2016 and 10/2016-09/2019

Director of the Institute of Organic Chemistry of Heidelberg University, Germany, 10/2019-09/2021

Vice Director of the Institute of Organic Chemistry of Heidelberg University, Germany, 10/2012-09/2013

Director of the International Scientific Forum Heidelberg (IWH) since August 2020

Since 2013 Member of the Board of Heidelberg University Hospital

Since 2004 Member of the South German Catalysis Institute (organized by Prof. J. Behm, Ulm)

Since 2007 part of the Catalysis Research Laboratory (CaRLa, co-operation BASF/ Heidelberg University)

since 2016 Director on the side of Heidelberg University

Founding member of the Hector Fellow Academy, https://www.hector-fellow-academy.de/en.html, 2013

Since 2020 Scientific Director of the International Scientific Forum Heidelberg (IWH)

2021 elected as a member of the Academia Europaea, a leading European Academy