【个人简历】 1998/9-2002/7：兰州大学 学士 2002/9-2005/7：兰州大学 硕士 导师：许鹏飞 教授 2005/9-2006/7： 中国科学院上海有机化学研究所 研究实习员 导师：俞飚 院士 2006/8-2010/6: 香港中文大学 博士 导师：谢作伟 院士 2010/7-2012/6：香港中文大学 博士后 导师：谢作伟 院士 2012/7-2023/7：中国科学院上海有机化学研究所 副研究员、研究员 2023/8-至今：上海大学 教授 【研究方向】 碳硼烷官能团化方法学，碳硼烷功能材料，不对称催化 【获奖情况】 2020年 国家“四青”人才 2019年 教育部高等学校科学研究优秀成果奖 自然科学二等奖（第三完成人） 2018年 Thieme Chemistry Journals Award 2016年 上海市青年拔尖人才 2014年 中科院卢嘉锡青年人才奖 2014年 中科院卓越青年科学家计划 2014年 中科院青年创新促进会 2013年 上海市浦江人才 2011年 Springer Thesis Award 【科研项目】 1. 国家自然科学基金委面上项目(22371290)，2024-2027，主持 2. 国家自然科学基金委重大研究计划培育项目(92056106)，2021-2023，主持 3. 国家自然科学基金委面上项目(21772223)，2018-2021，主持 4. 国家自然科学基金委面上项目(21372245)，2014-2017，主持 5. 上海市科学技术委员会澳台合作项目(18590760800)，2018-2021，主持 6. 上海市科学技术委员会自然科学基金青年项目(13ZR1465000)，2013-2016，主持 【主要论文】第一作者或通讯作者文章(按时间倒序排列) 1.Zhang, H.; Zhang, J.; Qiu, Z.*; Xie, Z.* Enantioselective Alkenylation of o-Carboranes via Ir-Catalyzed Asymmetric B–H Activation. ACS Catal. 2023, 13, 13856−13862. 2.Nie, Z.; Cheng, R.; Qiu, Z.*; Xie, Z.* Reaction of 4-Bpin-o-Carborane with Ketones: Sequential Carbon Vertex Alkylation and B-B Bond Activation. Chem Asian J. 2023, e202300598. 3.Jia, H.; Qiu, Z.* Recent Advances in Transition Metal-Catalyzed B-H Bond Activation for Synthesis of o-Carborane Derivatives with B-Heteroatom Bond. Chin. J. Org. Chem. 2023, 43, 1045−1068. 4.Zhang, H.; Cheng, R.; Qiu, Z.*; Xie, Z.* Iridium-Catalyzed Regioselective B(3,6)-Dialkenylation or B(4)-Alkenylation of o-Carboranes via B–H Activation and 1,2-Carbon Migration of Alkynes. Chem. Commun. 2023, 59, 740−743. 5.Qiu, Z.; Xie, Z.* Functionalization of o-Carboranes via Carboryne Intermediates. Chem. Soc. Rev. 2022, 51, 3164−3180. 6.Ge, Y.; Qiu, Z.*; Xie, Z. Pd-Catalyzed One-Pot Synthesis of Difunctionalized o-Carboranes via Construction of B−C and B−Heteroatom Bonds. Acta Chim. Sinica 2022, 80, 432−437. 7.Cheng, R.; Zhang, J.; Zhang, H.; Qiu, Z.*; Xie, Z.* Ir-Catalyzed Enantioselective B−H Alkenylation for Asymmetric Synthesis of Chiral-at-Cage o‑Carboranes. Nat. Commun. 2021, 12, 7146. 8.Qiu, Z.; Xie, Z.* A Strategy for Selective Catalytic B−H Functionalization of o‑Carboranes. Acc. Chem. Res. 2021, 54, 4065−4079. 9.Ge, Y.; Qiu, Z.*; Xie, Z. Pd-Catalyzed Selective Tetrafunctionalization of Diiodo-o-carboranes. Chem. Commun. 2021, 57, 8071–8704. 10.Ge, Y.; Zhang, J.; Qiu, Z.*; Xie, Z.* Pd-Catalyzed Sequential B(3)–I/B(4)–H Bond Activation for the Synthesis of 3,4-Benzo-o-Carboranes. Dalton Trans. 2021, 50, 1766–1773. 11.Zhang, H.; Qiu, Z.*; Xie, Z.* Recent Advances in Transition Metal-Promoted Multicomponent Cascade Reactions for Controlled Synthesis of Complex Carborane Derivatives. Chin. J. Org. Chem. 2020, 40, 3203–3213. 12.Cheng, R.; Qiu, Z.*; Xie, Z.* Palladium-Catalyzed Oxidative Annulation of 1-Hydroxy-o-Carborane with Internal Alkynes: Facile Synthesis of Carborane-Fused Oxaboroles. Chin. J. Chem. 2020, 38, 1575–1578. 13.Cheng, R.; Qiu, Z.*; Xie, Z.* Iridium-Catalyzed Regioselective B(3)-Alkenylation/B(3,6)-Dialkenylation of o-Carboranes via Direct B–H Activation. Chem. Eur. J. 2020, 26, 7212–7218. 14.Ge, Y.; Zhang, J.; Qiu, Z.*; Xie, Z.* Pd-Catalyzed Selective Bifunctionalization of 3-Iodo-o-Carborane via Pd Migration. Angew. Chem. Int. Ed. 2020, 59, 4851−4855. 15.Cui, C.-X.; Zhang, J.; Qiu, Z.*; Xie, Z.* Palladium-Catalyzed Intramolecular Dehydrogenative Coupling of BH and OH: Synthesis of Carborane-Fused Benzoxaboroles. Dalton Trans. 2020, 49, 1380–1383. 16.Cheng, R.; Li, B.; Wu, J.; Zhang, J.; Qiu, Z.*; Tang, W.; You, S.-L.; Tang, Y.; Xie, Z.* Enantioselective Synthesis of Chiral-at-Cage o-Carboranes via Pd-Catalyzed Asymmetric B–H Substitution. J. Am. Chem. Soc. 2018, 140, 4508−4511. 17.Xu, X.; Cheng, R.; Qiu, Z.*; Pan, C.* Palladium-Catalyzed Cross-Coupling Reactions of Borylated o-Carborane: Synthesis of 3,6-Diaryl-o-carboranes. Chin. J. Org. Chem. 2018, 38, 3078−3085. 18.Zhang, R,; Yuan, Y.; Qiu, Z.*; Xie, Z.* Reaction of o-Carboryne with Furans: Facile Synthesis of Carborane-Fused Oxanorbornenes and Their Derivatives. Chin. J. Chem. 2018, 36, 273–279. 19.Cui, C.-X.; Ren, S.; Qiu, Z.*; Xie, Z.* Synthesis of Carborane-Fused Carbo- and Heterocycles via Zirconacyclopentane Intermediate. Dalton Trans. 2018, 47, 2453–2459. 20.Zhang, J.; Qiu, Z.*; Xie, Z.* Broad Scope [4 + 2] Cycloaddition of o-Carboryne with Pentafulvenes Using 1-Li-2-OTf-o-C2B10H10 as Precursor. Organometallics, 2017, 36, 3806–3811. 21.Cheng, R.; Qiu, Z.*; Xie, Z. Iridium-Catalyzed Regioselective Borylation of Carboranes via Direct B–H Activation. Nat. Commun. 2017, 8, 14827. 22.Cheng, R.; Zhang, J.; Zhang, J.; Qiu, Z.*; Xie, Z.* Facile Synthesis of N-Carboranyl Amines through an ortho-Carboryne Intermediate. Angew. Chem. Int. Ed. 2016, 55, 1751–1754. 23.Qiu, Z.* Recent Advances in Transition Metal-Mediated Functionalization of o-Carboranes. Tetrahedron Lett. 2015, 56, 963–971. 24.Zhang, J.; Qiu, Z.*; Xu, P.-F.*; Xie, Z. Diels–Alder Reaction of o-Carboryne with Fulvenes: Synthesis of Carboranonorbornadienes and Their Transformations. ChemPlusChem 2014, 79, 1044–1052. 25.Qiu, Z.*; Xie, Z.* Generation and Reactivity of o-carborynes. Dalton Trans. 2014, 43, 4925–4934. 26.Qiu, Z.; Quan, Y.; Xie, Z.* Palladium-Catalyzed Selective Fluorination of o-Carboranes. J. Am. Chem. Soc. 2013, 135, 12192–12195. 27.Qiu, Z.; Deng, L.; Xie, Z.* Reaction of Li2C2B10Me8H2 with NiCl2. Ligand Effects on Stability of Ni-Octamethylcarboryne Complexes. J. Organomet. Chem. 2013, 747, 225–228. 28.Qiu, Z.; Ren, S.; Xie, Z.* Transition Metal-Carboryne Complexes: Synthesis, Bonding, and Reactivity. Acc. Chem. Res. 2011, 44, 299–309. 29.Qiu, Z.; Xie, Z.* Palladium/Nickel-Cocatalyzed Cycloaddition of 1,3-Dehydro-o-carborane with Alkynes. Facile Synthesis of C,B-Substituted Carboranes. J. Am. Chem. Soc. 2010, 132, 16085–16093. 30.Qiu, Z.; Deng, L.; Chan, H.-S.; Xie, Z.* Synthesis and Structural Characterization of Group 10 Metal−Carboryne Complexes. Organometallics 2010, 29, 4541–4547. 31.Qiu, Z.; Wang, S. R.; Xie, Z.* Nickel-Catalyzed Regioselective [2+2+2] Cycloaddition of Carboryne with Alkynes. Angew. Chem. Int. Ed. 2010, 49, 4649–4652. 32.Qiu, Z.; Sun, Y.; Xie, Z.* Reaction of [η5:σ-Me2C(C5H4)(C2B10H10)]Ru(NCCH3)2 with Internal Alkynes: Synthesis and Structural Characterization of Ruthenium-Cyclobutadiene and Ruthenacyclopentatriene Complexes. Sci. China Chem. 2010, 53, 2123–2128. 33.Qiu, Z.; Xie, Z.* Unique Chemical Properties of Metal–Carbon Bonds in Metal-Carboranyl and Metal-Carboryne Complexes. Sci. China Ser. B-Chem. (Review) 2009, 52, 1544–1558. 34.Qiu, Z.; Xie, Z.* Nickel-Catalyzed Three-Component [2+2+2] Cycloaddition Reaction of Arynes, Alkenes, and Alkynes. Angew. Chem. Int. Ed. 2009, 48, 5729–5732. 35.Qiu, Z.; Xie, Z.* Nickel-Mediated Three-Component Cycloaddition Reaction of Carboryne, Alkenes, and Alkynes. J. Am. Chem. Soc. 2009, 131, 2084–2085. 36.Qiu, Z.; Xie, Z.* Nickel-Mediated Coupling Reactions of Carboryne with Alkenes: A Synthetic Route to Alkenylcarboranes. Angew. Chem. Int. Ed. 2008, 47, 6572–6575. 37.Qiu, Z.; Zhang, H.; Hui, X.; Xu, P.-F.*; Wang, Q.*; Du, Y.; Yang, Y. Synthesis of 3-Thioheterocycloyl-1,3,4,5-tetrahdro-2-oxo-1H-benazepine. Chin. J. Org. Chem. 2007, 27, 607–618. 【主要著作】 1.Qiu, Z.; Xie, Z.* Transition-Metal-Promoted Functionalization of Carboranes. In Advances in Organometallic Chemistry and Catalysis: The Silver/Gold Jubilee International Conference on Organometallic Chemistry Celebratory Book; Pombeiro, A. J. L. Ed.; Wiley: New Jersey, 2014; Chapter 7. 2.Qiu, Z. Late Transition Metal-Carboryne Complexes: Synthesis, Structure, Bonding, and Reaction with Alkenes and Alkynes. Springer Theses. Springer: Berlin Heidelberg, 2012.
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