【个人简历】 2007.09-2013.07 北京化工大学 学士，硕士 导师：许家喜教授 2013.09-2016.07 北京大学 博士 导师：焦宁教授 2016.08-2017.08 北京大学 研究助理 合作导师：焦宁教授 2017.10-2020.08 慕尼黑工业大学 博士后，洪堡学者 合作导师：Thorsten Bach教授 2021.03-至今 上海大学 特聘教授 【论文著作】 第一作者（及共同一作）： 1. Li, X. Y.; Großkopf, J.; Jandl, C.; Bach, T. Enantioselective Visible Light-mediated Aza-Paternò-Büchi Reactions of Quinoxalinones. Angew. Chem. Int. Ed. 2021, 60, 2684–2688. 2. Li, X. Y.; Kutta, R. J.; Jandl, C.; Bauer, A.; Nuernberger, P.; Bach, T. Photochemically Induced Ring Opening of Spirocyclopropyl Oxindoles: Evidence for a Triplet 1,3-Diradical Intermediate and Deracemization by a Chiral Sensitizer. Angew. Chem. Int. Ed. 2020, 59, 21640–21647. (Hot Paper) 3. Pan, J.;† Li, X. Y.;† Lin, F.; Liu, J.; Jiao, N. Chemoselective Nitrosylation of Anilines and Alkynes via Fragmentary or Complete NO Incorporation. Chem. 2018, 4, 1427–1442. (†共同一作) 4. Liang, Y.-F.;† Li, X. Y.;† Wang, X. Y.; Zou, M. C.; Tang, C. H.; Liang, Y. J.; Song, S.; Jiao, N. Conversion of Simple Cyclohexanones into Catechols. J. Am. Chem. Soc. 2016, 138, 12271−12277. (†共同一作) 5. Li, X. Y.; Li, X. W.; Jiao, N. Rh-Catalyzed Construction of Quinolin-2(1H)-ones via C−H Bond Activation of Simple Anilines with CO and Alkynes. J. Am. Chem. Soc. 2015, 137, 9246−9249. 6. Sun, X.;† Li, X. Y.;† Song, S.; Zhu, Y. C.; Liang, Y. F.; Jiao, N. Mn-Catalyzed Highly Efficient Aerobic Oxidative Hydroxyazidation of Olefins: A Direct Approach to β-Azido Alcohols. J. Am. Chem. Soc. 2015, 137, 6059−6066. (†共同一作) 7. Chen, F.;† Huang, X. Q.;† Li, X. Y.;† Shen, T.; Zou, M. C.; Jiao, N. Dehydrogenative N-Incorporation: A Direct Approach to Quinoxaline N-Oxides under Mild Conditions. Angew. Chem. Int. Ed. 2014, 53, 10495–10499. (†共同一作) 8. Wen, X. J.;† Li, X. Y.;† Luo, X.; Wang, W. J.; Song, S.; Jiao, N. Intramolecular Csp -H/C-C Bond Amination of Alkyl Azides for the Selective Synthesis of Cyclic Imines and Tertiary Amines. Chem. Sci. 2020, 11, 4482−4487. (†共同一作) 9. Li, X. Y.; Pan, J.; Wu, H.; Jiao, N. Rh-catalyzed Aerobic Oxidative Cyclization of Anilines, Alkynes, and CO. Chem. Sci. 2017, 8, 6266−6273. 10. Li, X. Y.; Pan, J.; Song, S.; Jiao, N. Pd-catalyzed Dehydrogenative Annulation Approach for the Efficient Synthesis of Phenanthridinones. Chem. Sci. 2016, 7, 5384−5389 (ISACS19: Challenges in Organic Chemistry). 11. Li, X. Y.; Jandl, C.; Bach, T. Visible-Light-Mediated Enantioselective Photoreactions of 3‑Alkylquinolones with 4‑O‑Tethered Alkenes and Allenes. Org. Lett. 2020, 22, 3618−3622. 12. Li, X. Y.; Jandl, C.; Bach, T. Synthesis of Azocane- and Oxocane-annulated Furans by a [2+2] Photo­cycloaddition-Ring Opening Cascade. Synthesis 2021, 53, 723−730. 13. Li, X. Y.; Jiao, N. Reoxidation of Transition-metal Catalysts with O2. Chin. J. Chem. 2017, 35, 1349–1365. 14. Li, X. Y.;† Jin, X.;† Xu, J. X. Annuloselectivity in Reactions of Diacyl Dichlorides and Imines: Combined Experimental and Theoretical Studies. J. Org. Chem. 2015, 80, 6976−6985. (†共同一作) 15. Hou, S.;† Li, X. Y.;† Xu, J. X. N[1,3]-sigmatropic Shift in the Benzidine Rearrangement: Experimental and Theoretical Investigation. Org. Biomol. Chem. 2014, 12, 4952−4963. (†共同一作) 16. Li, X. Y.; Xu, J. X. DFT and Experimental Exploration of Intramolecular [2+2+2] Cycloaddition of Oxanorbornadienedicarboxylates and Analogues. J. Org. Chem. 2013, 78, 3039−3047. 17. Li, X. Y.; Xu, J. X. Annuloselectivity in Cycloadditions of Ketenes with Imines: A DFT Study. J. Org. Chem. 2013, 78, 347−355. 18. Li, X. Y.; Yang, Z. Y.; Xu, J. X. Comprehensive Theoretical Investigation on the Regioselectivity in the Nucleophilic Ring Opening of Epoxides. Curr. Org. Synth. 2013, 10, 169–177. 19. Li, X. Y.; Xu, J. X. Theoretical insights into the [4+2]/retro [4+2] cycloaddition approach to the synthesis of biaryls and polycyclic aromatics. Sci. China Chem. 2013, 56, 633–640. 20. Li, X. Y.; Xu, J. X. Theoretical Insights into the Metal-free and Formal [2+2+2] Cycloaddition Strategy via Intramolecular Cascade Propargylic ene/Diels–Alder Reactions with Tautomerization. Org. Biomol. Chem. 2011, 9, 5997–6003. 21. Qi, H. Z.;† Li, X. Y.;† Xu, J. X. Stereoselective Control in the Staudinger Reactions Involving Monosubstituted Ketenes with Electron Acceptor Substituents: Experimental Investigation and Theoretical Rationalization. Org. Biomol. Chem. 2011, 9, 2702–2714. (†共同一作) 22. Li, X. Y.; Xu, J. X. Theoretical Calculational Investigation on the Regioselectivity of the Ring Opening of Thiiranes with Ammonia and Amines.Tetrahedron 2011, 67, 1681–1688. 23. Li, X. Y.; Xu, J. X. Abundant Intramolecular Ring Rearrangements of 1-(N-Benzyloxycarbonylamino)- arylmethylphosphonate Phenyl monoesters Under Electrospray Ionization Conditions. Phosphorus, Sulfur, and Silicon, 2011, 186, 503–510. 24. Li, X. Y.; Chen, N.; Xu, J. X. An Improved and Mild Wenker Synthesis of Aziridines. Synthesis 2010, 20, 3423-3428. 其它代表性文章： 25. Song S.; Li, X. Y.; Wei, J.; Wang, W.; Zhang, Y.; Ai, L.; Zhu, Y.; Shi, X.; Zhang, X.; Jiao, N. DMSO-catalysed late-stage chlorination of (hetero)arenes. Nat. Catal. 2020, 3, 107–115. 26. Huang, X.; Li, X. Y.; Xie, X.; Harms, K.; Riedel, R.; Meggers, E. Catalytic asymmetric synthesis of a nitrogen heterocycle through stereocontrolled direct photoreaction from electronically excited state. Nat. Commun. 2017, 8, 2245. 27. Huang, X. Q.; Li, X. Y.; Zou, M. C.; Song, S.; Tang, C. H.; Yuan, Y. Z.; Jiao, N. From Ketones to Esters by a Cu-Catalyzed Highly Selective C(CO)-C(alkyl) Bond Cleavage: Aerobic Oxidation and Oxygenation with Air. J. Am. Chem. Soc. 2014, 136, 14858–14865. 28. Li, X. W.; Lin, F.; Huang, K.; Wei, J.; Li, X. Y.; Wang, X.; Geng, X.; Jiao, N. Selective α-Oxyamination and Hydroxylation of Aliphatic Amides. Angew. Chem. Int. Ed. 2017, 56, 12307-12311. 29. Liu, J. Z.;† Wen, X. J.;† Qin, C.;† Li, X. Y.; Luo, X.; Sun, A.; Zhu, B.; Song, S.; Jiao, N. Oxygenation of Simple Olefins via Selective Allylic C-C Bond Cleavage: A Direct Approach to Cinnamyl Aldehydes, Angew. Chem. Int. Ed. 2017, 56. 11940-11944. 30. Huang, X. Q.; Li, X. Y.; Jiao, N. Copper-catalyzed Direct Transformation of Simple Alkynes to Alkenyl Nitriles via Aerobic Oxidative N incorporation. Chem. Sci. 2015, 6, 6355–6360. 31. Liang, Y. F.; Li, X. Y.; Wang, X. Y.; Yan, Y. P.; Feng, P.; Jiao, N. Aerobic Oxidation of PdII to PdIV by Active Radical Reactants: Direct C−H Nitration and Acylation of Arenes via Oxygenation Process with Molecular Oxygen. ACS Catal. 2015, 5, 1956−1963. 32. Wu, H.; Li, X.Y.; Yan, Z.; Ma, N.; Song, S.; Zhang, G.; Jiao, N. Cu(I)-Catalyzed [2 + 2 + 1] Cycloaddition of Amines, Alkynes, and Ketenes: An Umpolung and Regioselective Approach to Full-Substituted β-Pyrrolinones. Org. Lett. 2021, 23, 762–766. 33. Pan, J.; Li, X. Y.; Qiu, X.; Luo, X.; Jiao, N. Copper-Catalyzed Oxygenation Approach to Oxazoles from Amines, Alkynes, and Molecular Oxygen. Org. Lett. 2018, 20, 2762–2765. 34. Zhu, Y. C.; Li, X. Y.; Wang, X.; Huang, X.; Shen, T.; Zhang, Y.; Sun, X.; Song, S.; Jiao, N. Silver-Catalyzed Decarboxylative Azidation of Aliphatic Carboxylic Acids. Org. Lett. 2015, 17, 4702−4705. 35. Liang, Y.-F.; Wu, K.; Song, S.; Li, X. Y.; Huang, X.; Jiao, N. I2- or NBS-Catalyzed Highly Efficient α-Hydroxylation of Ketones with Dimethyl Sulfoxide. Org. Lett. 2015, 17, 876−879. 36. Feng, P.; Sun, X.; Su, Y.; Li, X. Y.; Zhang, L.−H.; Shi, X.; Jiao, N. Ceric Ammonium Nitrate (CAN) Catalyzed Modification of Ketones via Two C–C Bond Cleavages with the Retention of the Oxo-Group. Org. Lett. 2015, 17, 876−879. |