郦鑫耀

创建时间:  2021/03/26  张杰   浏览次数:   返回

郦鑫耀 个人简介 

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姓名:郦鑫耀

出生日期:1988.03

办公室:E510

职称:教授

学历:博士

职务:

通信地址:

电话:

Email:xinyaoli@shu.edu.cn

【个人简历】

2007.09-2013.07        北京化工大学      学士,硕士           导师:许家喜教授

2013.09-2016.07        北京大学         博士               导师:焦宁教授

2016.08-2017.08        北京大学         研究助理            合作导师:焦宁教授

2017.10-2020.08        慕尼黑工业大学    博士后,洪堡学者     合作导师:Thorsten Bach教授

2021.03-至今          上海大学         特聘教授

 

【论文著作】

第一作者(及共同一作):

1.     Li, X. Y.; Großkopf, J.; Jandl,   C.; Bach, T. Enantioselective Visible Light-mediated Aza-Paternò-Büchi   Reactions of Quinoxalinones. Angew. Chem. Int. Ed. 2021, 60, 26842688.

2.     Li, X. Y.; Kutta, R. J.; Jandl,   C.; Bauer, A.; Nuernberger, P.; Bach, T. Photochemically Induced Ring Opening   of Spirocyclopropyl Oxindoles: Evidence for a Triplet 1,3-Diradical   Intermediate and Deracemization by a Chiral Sensitizer. Angew. Chem. Int. Ed. 2020, 59, 21640–21647. (Hot Paper)

3.     Pan, J.; Li, X. Y.; Lin, F.; Liu, J.; Jiao,   N. Chemoselective Nitrosylation of Anilines and Alkynes via Fragmentary or   Complete NO Incorporation. Chem. 2018, 4, 1427–1442. (共同一作)

4.     Liang, Y.-F.; Li, X. Y.; Wang, X. Y.; Zou, M.   C.; Tang, C. H.; Liang, Y. J.; Song, S.; Jiao, N. Conversion of Simple   Cyclohexanones into Catechols. J. Am. Chem. Soc. 2016, 138,   1227112277. (共同一作)

5.     Li, X. Y.; Li, X. W.; Jiao, N.   Rh-Catalyzed Construction of Quinolin-2(1H)-ones via CH Bond Activation of   Simple Anilines with CO and Alkynes. J. Am. Chem. Soc. 2015, 137,   92469249.

6.     Sun, X.; Li, X. Y.; Song, S.; Zhu, Y. C.;   Liang, Y. F.; Jiao, N. Mn-Catalyzed Highly Efficient Aerobic Oxidative   Hydroxyazidation of Olefins: A Direct Approach to β-Azido Alcohols. J. Am.   Chem. Soc. 2015, 137, 60596066. (共同一作)

7.     Chen, F.; Huang, X. Q.; Li, X. Y.; Shen, T.; Zou, M. C.;   Jiao, N. Dehydrogenative N-Incorporation: A Direct Approach to Quinoxaline   N-Oxides under Mild Conditions. Angew. Chem. Int. Ed. 2014, 53, 10495–10499. (共同一作)

8.     Wen, X. J.; Li, X. Y.; Luo, X.; Wang, W. J.;   Song, S.; Jiao, N. Intramolecular Csp -H/C-C Bond Amination of Alkyl Azides   for the Selective Synthesis of Cyclic Imines and Tertiary Amines. Chem.   Sci. 2020, 11, 44824487. (共同一作)

9.     Li, X. Y.; Pan, J.; Wu, H.; Jiao,   N. Rh-catalyzed Aerobic Oxidative Cyclization of Anilines, Alkynes, and CO.   Chem. Sci. 2017, 8, 62666273.

10. Li, X. Y.; Pan, J.; Song, S.;   Jiao, N. Pd-catalyzed Dehydrogenative Annulation Approach for the Efficient   Synthesis of Phenanthridinones. Chem. Sci. 2016, 7, 53845389 (ISACS19:   Challenges in Organic Chemistry).

11. Li, X. Y.; Jandl, C.; Bach, T.   Visible-Light-Mediated Enantioselective Photoreactions of 3Alkylquinolones with 4OTethered Alkenes and   Allenes. Org. Lett. 2020, 22, 36183622.

12. Li, X. Y.; Jandl, C.; Bach, T. Synthesis of Azocane- and Oxocane-annulated Furans by a [2+2]   Photo­cycloaddition-Ring Opening Cascade. Synthesis 2021, 53, 723730.

13. Li, X. Y.; Jiao, N. Reoxidation of   Transition-metal Catalysts with O2. Chin. J. Chem. 2017, 35,   1349–1365.

14. Li, X. Y.; Jin, X.; Xu, J. X.   Annuloselectivity in Reactions of Diacyl Dichlorides and Imines: Combined   Experimental and Theoretical Studies. J. Org. Chem. 2015, 80,   69766985. (共同一作)

15. Hou, S.; Li, X. Y.; Xu, J. X.   N[1,3]-sigmatropic Shift in the Benzidine Rearrangement: Experimental and   Theoretical Investigation. Org. Biomol. Chem. 2014, 12,   49524963. (共同一作)

16. Li, X. Y.; Xu, J. X. DFT and   Experimental Exploration of Intramolecular [2+2+2] Cycloaddition of   Oxanorbornadienedicarboxylates and Analogues. J. Org. Chem. 2013,   78, 30393047.

17. Li, X. Y.; Xu, J. X.   Annuloselectivity in Cycloadditions of Ketenes with Imines: A DFT Study. J. Org. Chem. 2013, 78,   347355.

18. Li, X. Y.; Yang, Z. Y.; Xu, J. X.   Comprehensive Theoretical Investigation on the Regioselectivity in the   Nucleophilic Ring Opening of Epoxides. Curr. Org. Synth. 2013, 10,   169–177.

19. Li, X. Y.; Xu, J. X. Theoretical   insights into the [4+2]/retro [4+2] cycloaddition approach to the synthesis   of biaryls and polycyclic aromatics. Sci.   China Chem. 2013, 56, 633–640.

20. Li, X. Y.; Xu, J. X. Theoretical   Insights into the Metal-free and Formal [2+2+2] Cycloaddition Strategy via   Intramolecular Cascade Propargylic ene/Diels–Alder Reactions with   Tautomerization. Org. Biomol. Chem. 2011, 9, 5997–6003.

21. Qi, H. Z.; Li, X. Y.; Xu, J. X.   Stereoselective Control in the Staudinger Reactions Involving Monosubstituted   Ketenes with Electron Acceptor Substituents: Experimental Investigation and   Theoretical Rationalization. Org. Biomol. Chem. 2011, 9,   2702–2714. (共同一作)

22. Li, X. Y.; Xu, J. X. Theoretical Calculational   Investigation on the Regioselectivity of the Ring Opening of Thiiranes with   Ammonia and Amines.Tetrahedron 2011, 67, 1681–1688.

23. Li, X. Y.; Xu, J. X. Abundant   Intramolecular Ring Rearrangements of 1-(N-Benzyloxycarbonylamino)-   arylmethylphosphonate Phenyl monoesters Under Electrospray Ionization   Conditions. Phosphorus, Sulfur, and Silicon, 2011, 186,   503–510.

24. Li, X. Y.; Chen, N.; Xu, J. X. An Improved and Mild Wenker   Synthesis of Aziridines. Synthesis 2010, 20, 3423-3428.

其它代表性文章:

25. Song S.; Li, X. Y.;   Wei, J.; Wang, W.; Zhang, Y.; Ai, L.; Zhu, Y.; Shi, X.; Zhang, X.; Jiao, N. DMSO-catalysed late-stage   chlorination of (hetero)arenes. Nat. Catal. 2020, 3, 107115.

26. Huang, X.; Li, X.   Y.; Xie, X.; Harms, K.; Riedel, R.; Meggers, E. Catalytic asymmetric   synthesis of a nitrogen heterocycle through stereocontrolled direct   photoreaction from electronically excited state. Nat. Commun. 2017,   8, 2245.

27. Huang, X. Q.; Li,   X. Y.; Zou, M. C.; Song, S.; Tang, C. H.; Yuan, Y. Z.; Jiao, N. From   Ketones to Esters by a Cu-Catalyzed Highly Selective C(CO)-C(alkyl) Bond   Cleavage: Aerobic Oxidation and Oxygenation with Air. J. Am. Chem. Soc.   2014, 136, 14858–14865.

28. Li, X. W.; Lin, F.;   Huang, K.; Wei, J.; Li, X. Y.; Wang, X.; Geng, X.; Jiao, N.   Selective α-Oxyamination and Hydroxylation of Aliphatic Amides. Angew.   Chem. Int. Ed. 2017, 56, 12307-12311.

29. Liu, J. Z.; Wen, X. J.; Qin, C.; Li, X. Y.; Luo, X.; Sun, A.; Zhu,   B.; Song, S.; Jiao, N. Oxygenation of Simple Olefins via Selective Allylic   C-C Bond Cleavage: A Direct Approach to Cinnamyl Aldehydes, Angew. Chem.   Int. Ed. 2017, 56. 11940-11944.

30. Huang, X. Q.; Li,   X. Y.; Jiao, N. Copper-catalyzed Direct Transformation of Simple   Alkynes to Alkenyl Nitriles via Aerobic Oxidative N incorporation. Chem.   Sci. 2015, 6, 6355–6360.

31. Liang, Y. F.; Li,   X. Y.; Wang, X. Y.; Yan, Y. P.; Feng, P.; Jiao, N. Aerobic Oxidation   of PdII to PdIV by Active Radical Reactants: Direct CH Nitration and   Acylation of Arenes via Oxygenation Process with Molecular Oxygen. ACS   Catal. 2015, 5, 19561963.

32. Wu, H.; Li, X.Y.;   Yan, Z.; Ma, N.; Song, S.; Zhang, G.; Jiao, N. Cu(I)-Catalyzed [2 + 2 + 1]   Cycloaddition of Amines, Alkynes, and Ketenes: An Umpolung and Regioselective   Approach to Full-Substituted β-Pyrrolinones. Org. Lett. 2021, 23,   762–766.

33. Pan, J.; Li, X. Y.;   Qiu, X.; Luo, X.; Jiao, N. Copper-Catalyzed Oxygenation Approach to Oxazoles   from Amines, Alkynes, and Molecular Oxygen. Org. Lett. 2018, 20,   2762–2765.

34. Zhu, Y. C.; Li, X.   Y.; Wang, X.; Huang, X.; Shen, T.; Zhang, Y.; Sun, X.; Song, S.;   Jiao, N. Silver-Catalyzed Decarboxylative Azidation of Aliphatic Carboxylic   Acids. Org. Lett. 2015, 17, 47024705.

35. Liang, Y.-F.; Wu, K.;   Song, S.; Li, X. Y.; Huang, X.; Jiao, N. I2- or NBS-Catalyzed   Highly Efficient α-Hydroxylation of Ketones with Dimethyl Sulfoxide. Org.   Lett. 2015, 17, 876879.

36. Feng, P.; Sun, X.; Su,   Y.; Li, X. Y.; Zhang, L.H.; Shi, X.; Jiao, N. Ceric   Ammonium Nitrate (CAN) Catalyzed Modification of Ketones via Two C–C Bond   Cleavages with the Retention of the Oxo-Group. Org. Lett. 2015,   17, 876879.

 

 

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