【研究方向】

金属有机多孔材料的合成及应用

无机-有机杂化材料的结构设计与调控

【科研项目】

上海高校选拔培养优秀青年教师科研专项基金   项目负责人

上海大学创新基金   项目负责人

上海市自然科学基金   项目负责人

国家自然科学基金青年基金   项目负责人

中科院结构化学国家重点实验室基金   项目负责人

【部分论文著作】

1. Xiang He,* Xiao-Peng Lu, Zhan-Feng Ju, Chun-Ju Li, Qi-Kai Zhang, Ming-Xing Li*, Syntheses, structures, and photoluminescent properties of ten metal–organic frameworks constructed by a flexible tetracarboxylate ligand, CrystEngComm, 2013, 15, 2731–2744.

2. Xiang He,* Xiao-Peng Lu, Ming-Xing Li, Russell E. Morris, Tuning Different Kinds of Entangled Networks Formed by Isomers of Bis(1,2,4-triazol-1-ylmethyl)benzene and a Flexible Tetracarboxylate Ligand, Crystal Growth & Design, 2013, 13, 1649-1654.

3. Xiang He,* Xiao-Peng Lu, Yu-Yang Tian, Ming-Xing Li, Shourong Zhu, Feifei Xing and Russell E. Morris,, Controlling interpenetration in metal–organic frameworks by tuning the conformations of flexible bis(triazole) ligands, CrystEngComm, 2013, 15, 9437-9443.

4. Peng Yang, Meng-Si Wang, Jin-Jin Shen, Ming-Xing Li*, Zhao-Xi Wang, Min Shao, Xiang He* Seven novel coordination polymers constructed by rigid 4-(4-carboxyphenyl)terpyridine ligands: synthesis, structural diversity, luminescence and magnetic properties, Dalton Trans. 2014, 43(3), 1460-1470.

5. Jin-Jin Shen, Ming-Xing Li,* Zhao-Xi Wang, Chun-Ying Duan,* Shou-Rong Zhu, Xiang He* Unexpected 4-Fold [2+2] Interpenetration and Polycatenation Behaviors in Porous Luminescent Zinc Metal-Organic Frameworks Constructing from Flexible 3,5-Bis(4-pyridylmethoxy)benzoate Ligand, Crystal Growth & Design, 2014, 14, 2818−2830.

6. Tian Ma, Ming-Xing Li,*, Zhao-Xi Wang, Jin-Cang Zhang, Min Shao, and Xiang He* Structural Diversity, Luminescence, and Magnetic Properties of Eight Co(II)/Zn(II) Coordination Polymers Constructed from Semirigid Ether-Linked Tetracarboxylates and Bend Dipyridyl-Triazole Ligands Crystal Growth & Design, 2014, 14, 4155−4165.

7 Xiang He,* Kang Fang, Xiao-Hai Guo, Jing Han*, Xiao-Peng Lu and Ming-Xing Li, A homochiral Cu(I) coordination polymer based on achiral precursors and its photocatalytic properties, Dalton Trans. 2015, 44, 13545-13549.

8. Xiang He*, Qian Luo, Kang Fang, Zhiming Duan, Zhanfeng Ju*, Asymmetric and symmetric occupation of active sites in porous copper(II) metal-organic frameworks with their gas absorption, Microporous and Mesoporous Materials 2015, 218, 1-6.

9. Weiting Yang, Hong-Rui Tian, Jian-Ping Li, Yuan-Feng Hui, Xiang He*, Jiyang Li, Song Dang, Zhigang Xie, Zhong-Ming Sun*, Photochromic Terbium Phosphonates with Photomodulated Luminescence and Metal Ion Sensitive Detection, Chem. Eur. J. 2016, 22, 15451–15457.

10. Chao Wang, Chao Liu, Xiang He*, Zhong-Ming Sun*, A cluster-based mesoporous Ti-MOF with sodalite supercages, Chem. Commun. 2017, 53, 11670–11673.

11. Sheng-Quan Lu, Yong-Yao Liu, Zhi-Ming Duan, Zhao-Xi Wang, Ming-Xing Li, and Xiang He*, Improving Water-Stability and Porosity of Lanthanide Metal−Organic Frameworks by Stepwise Synthesis for Sensing and Removal of Heavy Metal Ions, Cryst. Growth Des. 2018, 18, 4602−4610.

12. Sheng-Quan Lu, Kang Fang, Yong-Yao Liu, Ming-Xing Li, Sui-Jun Liu* and Xiang He*, Multivariant synthesis, crystal structures and properties of four nickel coordination polymers based on flexible ligands, CrystEngComm, 2018, 20, 5045-5055.

13. Yanan Si, Xiang He*, Jie Jiang, Zhiming Duan, Wenjing Wang, and Daqiang Yuan*, Highly effective H2/D2 separation in a stable Cu-based metal-organic framework, Nano Research, 2021, 14, 518–525.

14 Rui Liu, Xiang He*, Miao Miao, Shaomei Cao and Xin Fen*, In-Situ Growth of Porous Cu₃(BTC)₂ on Cellulose Nanofibrils for Ultra-Low Dielectric Films with High Flexibility, J. Mater. Sci. Technol. 2022, 112, 202−211.

15 Yongyao Liu, Zhonglin Li, Yuejiang Han, Zhenyu Ji, Hengbo Li, Yuanzheng Liu, Yifan Wei, Cheng Chen, Xiang He*, Mingyan Wu*, Highly Stable Metal–Organic Framework with Redox-Active Naphthalene Diimide Core as Cathode Material for Aqueous Zinc-Ion Batteries, ChemSusChem. 2023, 16, e202202305.